Product ID:FORMULA 190
MSDS Date:02/01/1994
FSC:6840
NIIN:00N010002
MSDS Number: CFNMX

STATE CHEMICAL MFG CO

3100 HAMILTON BLVD
CLEVELAND, OH 44114
US

Emergency Phone: 216-861-7114

Info Phone: 216-861-7114

Cage: 53798

STATE CHEMICAL MANUFACTURING CO.

CLEVELAND, OH 44114-3701 US

Telephone: 216-861-7114

Cage: 53798

DIESEL FUELS; (PETROLEUM DISTILLATE)

CAS: 68334-30-5

RTECS: HZ1800000

Fraction By Weight: 92.67%

OSHA PEL N/K

ACGIH TLV: N/K

TRIPROPYLENE GLYCOL

CAS: 24800-44-0

RTECS: YK6825000

OSHA PEL N/K

ACGIH TLV: N/K

LAUNDRY. READ & FOLLOW ALL LABEL DIRECTIONS &

RTECS: 9999999ZZ

ARE INTENDED FOR INDUSTRIAL & INSTITUTIONAL USE

RTECS: 9999999ZZ

REACH OF CHILDREN.

RTECS: 9999999ZZ

ACETIC ACID, (2,4-DICHLOROPHENOXY)-, ISOOCTYL ESTER;

CAS: 25168-26-7

RTECS: AG8575000

Fraction By Weight: 1.09%

OSHA PEL N/K

ACGIH TLV: 10 MG/M3

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

URACIL, 5-BROMO-3-SEC-BUTYL-6-METHYL-; (BROMACIL)

CAS: 314-40-9

RTECS: YQ9100000

Fraction By Weight: 0.98%

OSHA PEL 1 PPM

ACGIH TLV: 10 MG/M3

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYE IRRITANT. SKIN IRRITANT. POSSIBLE
CAUSE OF DERMATITIS. VAPORS ARE IRRITATING TO NOSE AND THROAT.
HARMFUL OR FATAL IF SWALLOWED. OVEREXPOSURE MAY CAUSE NAUSEA,
VOMITING, BURNING OF EYES AND/OR SKIN . ASPIRATION INTO LUNGS
CAUSES CHEMICALPNEUMONIA. CHRONIC: CENTRAL NERVOUS SYSTEM
DEPRESSION AND (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: INTERNAL ORGAN DAMAGE. 2,4-D IS A
SUSPECT CARCINOGEN.
Medical Cond Aggravated by Exposure:BRONCHIAL CONDITIONS. SKIN
IRRITATION AND DERMATITIS. EYE IRRITATION.

First Aid:INGEST: DO NOT INDUCE VOMITING. GIVE WATER OR MILK TO DILUTE.
ASPIRATION HAZARD DUE TO PETROLEUM DISTILLATES PRESENT. CONTACT MD
IMMED. INHAL: REMOVE TO FRESH AIR. USE ARTIFICIAL RESPIRATION IF
NECESS ARY. GET MED ATTN IMMED. EYES: FLUSH EYES IMMED W/PLENTY OF
COOL WATER FOR AT LEAST 15 MIN. GET MED ATTN IMMED. SKIN: WASH WELL
WITH SOAP & WATER. REMOVE CONTAMINATED SHOES &/OR CLOTHING.

Flash Point Method:TCC
Flash Point:150F,66C
Lower Limits:0.6%
Upper Limits:7.5%
Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, FOAM AND WATERFOG.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROT EQUIP . A
STRAIGHT WATER STREAM MAY SPREAD FIRE HOWEVER, WATER SPREAD FROM AS
FAR A DISTANCE AS POSSIBLE MAY (SUPDAT)
Unusual Fire/Explosion Hazard:VAPORS AVE HEAVIER THAN AIR & MAY TRAVEL
A CONSIDERABLE DISTANCE FROM IGNITION & FLASHBACK. CNTNRS INVOLVED
IN FIRE MAY RUPTURE OR EXPLODE. AVOID DENSE (SUPDAT)

Spill Release Procedures:REMOVE SOURCES OF HEAT, SPARKS OR OPEN FLAMES.
VENT AREA. DIKE AREA TO CONTAIN SPILL. USE ABSORB TO COLLECT SPILL
OR COLLECT IT BY VACUUMING. DISPOSE OF SPILLED MATL APPROP.
REPORTABLE QTY OF 2,4-D IS 100 LBS (1264 GALS OF PROD). PRODUCT IS
(SUPDAT)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:DO NOT STORE NEAR HEAT, SPARKS OR OPEN
FLAMES. DO NOT STORE NEAR GOOD FEED/FERTILIZERS. STORE ONLY IN
ORIGINAL LABELED CNTNR. STORE ABOVE 40F (SUPDAT)
Other Precautions:DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
WASH HANDS & OTHER EXPOSED AREAS WITH SOAP AND WATER BEFORE EATING,
DRINKING OR SMOKING TO PREVENT ACCIDENTAL INGESTION. WASH
CONTAMINATED CLOTHING SEPARATELY FROM OTHER HOUSEHOLD (ING 5)

Respiratory Protection:WEAR NIOSH APPROVED RESPIRATOR IF TLV IS
EXCEEDED AND/OR TO AVOID BREATHING SPRAY MIST.
Ventilation:USE ONLY OUTDOORS IN FRESH AIR.
Protective Gloves:RUBBER GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER .
RUBBER BOOTS IF NECESSARY TO AVOID WETTING SKIN.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
PH: N/A (NONAQ). FIRE FIGHT PROC: BE USED TO COOL CNTNRS INVOLVED IN
FIRE. USE ADEQUATE PROT EQUIP WHEN FIRE FIGHTING. DO NOT INHALE. DO
NOT INHALE SMOKE, FUMES, VAPORS OR COMBUSTION PRODUCTS. EXPLO H AZ:
ACCUMULATION OF VAPORS. SPILL PROC:TOX TO FISH & WILDLIFE.
HNDLG/STOR PRECS: TO AVOID PROD SEPARATION.

Boiling Pt:B.P. Text:325F,163C
Spec Gravity:0.874 (H*2O=1)
pH:SUPDAT
Solubility in Water:NEGLIGIBLE
Appearance and Odor:CLEAR AMBER LIQUID WITH PETROLEUM ODOR.
Percent Volatiles by Volume:>95 WT

Stability Indicator/Materials to Avoid:YES
STRONG ACIDS OR BASES, SELECT AMINES, STRONG OXIDIZING REAGENTS.
Stability Condition to Avoid:IGNITION SOURCES, ELECTRICAL AREAS, HEAT,
SPARKS AND OPEN FLAMES.
Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE,
HYDROGEN CHLORIDE AND NITROGEN CONTAINING GASES.

Waste Disposal Methods:2,4-D IS ACUTE HAZARDOUS WASTE UNDER RCRA.
FOLLOW LABEL DISPOSAL INSTRUCTIONS. DO NOT REUSE EMPTY CONTAINERS
FOR ANY PURPOSE. FOLLOW ALL FEDERAL, STATE AND LOCAL REGULATIONS
REGARDING WASTE DISPOSAL.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.